The purpose of this special issue is to provide a curated resource for warming-induced greenhouse gas emissions from both empirical and modelling studies to help understand their response to climate overshoot and their implications for climate stabilization.

This special issue presents results from the Ocean Alkalinity Enhancement Pelagic Impact Intercomparison Project (OAEPIIP), an international effort to assess the biological, ecological, and biogeochemical impacts of ocean alkalinity enhancement (OAE) on natural plankton communities. OAEPIIP adopted a standardized experimental design that has been implemented by research teams worldwide, enabling direct comparison of responses across diverse marine environments. Submissions are welcome from studies that align with (or inform) the OAEPIIP framework.

Mercury (Hg) is a chemical pollutant of human health concern worldwide; a consequence of anthropogenic activities; and the focus of the Minamata Convention on Mercury (MC; https://minamataconvention.org/en), an international treaty to protect human health and the environment from the adverse effects of mercury. The MC entered into force on 16 August 2017 and committed to limiting the use and environmental release of mercury. Also, the 1998 Protocol on Heavy Metals of the 1979 Convention on Long-Range Transboundary Air Pollution (LRTAP) commits parties to mitigating emissions of mercury (as well as cadmium and lead) from a variety of point sources and provides guidance on mitigating emissions associated with heavy metal use in manufactured products. The MC framework requires an evaluation of the effectiveness of its measures in meeting the objectives beginning no later than 6 years after the convention’s entry into force and periodically thereafter. The Protocol on Heavy Metals requires a periodic review of the progress towards meeting the obligations in the protocol and the sufficiency and effectiveness of those obligations and an evaluation of whether additional emission reductions are warranted.

This multi-journal special issue (SI) is intended to develop the required information that can be scientifically exploited to address key policy questions of the conventions: (1) what are the contributions of anthropogenic emissions and releases and other Hg sources to current Hg levels observed in air, biota, humans, and other media? (2) How have these contribution levels changed over time and over the timeline of the convention? (3) How do the contribution levels and their trends vary geographically at the global scale? (4) What are the contributions of anthropogenic emissions and releases and other drivers to the temporal trends in observed Hg levels across global regions? (5) How are observed Hg levels expected to change in the future?

The special issue aims at collecting relevant research advances arising from the design, implementation, and results of the Multi-Compartment Hg Modeling and Analysis Project (MCHgMAP) and from the scientific community on all aspects of biogeochemical mercury cycling, including primary and secondary emissions, observations, process studies, and single to multi-compartmental and statistical model development and application. A challenge of analysing the fate of emitted mercury is that it can recycle between the atmosphere, land, and ocean, and as a result, past and present emissions can continue to affect the environment on timescales of decades to centuries. MCHgMAP is an ensemble modelling initiative developed to inform the effectiveness of evaluations of the MC and LRTAP, utilizing a coordinated modelling approach between single-medium (atmosphere, land, and ocean) and multi-media mercury models to consistently simulate the changing global and regional environmental Hg cycling and analyse its drivers. The SI includes an overview paper on MCHgMAP, describing its scientific background and design (an important and crucial preparatory stage), which will be referenced by the individual papers on this project that follow.

The Peruvian upwelling system is one of the most productive ecosystems in the ocean. Continuous upwelling of nutrient-rich water generates high primary production, supporting an efficient food web and leading to high fishery yields. An extensive oxygen minimum zone underlying the productive surface waters gives rise to high losses of fixed nitrogen via denitrification and anaerobic ammonium oxidation. This results in nutrient ratios of upwelled waters deviating strongly from Redfield stoichiometry, with a high N deficit and excess P. How this unusual nutrient stoichiometry affects plankton community production and succession and how this feeds back on biogeochemical cycling are still not well understood. To address these questions, an in situ mesocosm experiment was conducted in the coastal upwelling system off Peru in the framework of the Collaborative Research Center 754 "Climate-Biogeochemistry Interactions in the Tropical Ocean". The field experiment took place from January to April 2017 during a coastal El Niño, a rare event of El Niño conditions confined to Peruvian coastal waters. Key objectives of this mesocosm study, which involved 57 researchers from 10 nations, were to unravel the interplay of pelagic ecology and biogeochemistry under the unique environmental conditions of the Peruvian upwelling system. This special issue in Biogeosciences is intended as a collective outlet for publications resulting from this study, covering the broad range of research topics from seawater chemistry to plankton ecology and pelagic biogeochemistry.